The 2009 Emmy Awards Sunday evening did not feature our favorite show nominated in any major categories, but Chuck and Blair were named the TV's #1 hottest couple during E!'s Emmy pre-show at least. Goooo Chair!

Also, the Gossip Girl cast's two leading ladies were on hand for the festivities, looking totally fabulous on the red carpet as you might expect.

Here's Leighton Meester in white and Blake Lively in red. Whose dress do you like better? Vote in our fashion survey below and let us know!

Which Gossip Girl star looked better at the 2009 Emmys?

Steve Marsi is the Managing Editor of TV Fanatic. Follow him on Google+ or email him here.