Steve Buscemi is seen here as the one and only Nucky Thompson. It's a photo from "What Does the Bee Do?"
You're looking a a scene from "What Does the Bee Do?." It's the fourth episode of season two.
Chalky is no longer in jail. But the guy still feels like his life is a prison.

Boardwalk Empire Season 2 Episode 4 Quotes

Mickey: From the tiny acorn grows the mighty elk.
Jimmy: If you had a brain, you'd be dangerous.

I didn't spend my life getting groped by a bunch of drunks to wind up in a goddamn poor house.