This is a nice close-up of Ichabod. It is from the Sleepy Hollow episode "Necromancer."
Abbie looks for help concerning her sister on Sleepy Hollow. "Into the Darkness" is the eighth episode of the show's first season.

Sleepy Hollow Season 1 Episode 8 Quotes

Irving: A dead guy, a mental patient and a time traveler from the Revolution.
Abbie: That's our team.

I can hardly believe Jefferson foresaw holding a headless gentleman prisoner.