This is a nice close-up of Ichabod. It is from the Sleepy Hollow episode "Necromancer."
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Abbie looks for help concerning her sister on Sleepy Hollow. "Into the Darkness" is the eighth episode of the show's first season.
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Sleepy Hollow Season 1 Episode 8 Quotes

Irving: A dead guy, a mental patient and a time traveler from the Revolution.
Abbie: That's our team.

I can hardly believe Jefferson foresaw holding a headless gentleman prisoner.

Irving