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I don't know if I can come up with 10 and I"m not sure about the order but here it goes:
Mer/Christina (twisted sisters...best relationship)
Richard/Mer (Surrogate father/daughter)
Always liked Scott Foley (all the way back to the Felicity days) and I like this couple but I fear they will not have a happy end. I feel a Denny like story coming....hope I'm wrong.