After two seasons of captivating us with chemistry and romantic near-misses, Chuck and Blair are finally together and plan on keeping it that way for the foreseeable future, despite trust issues sparked by a same-sex kiss.

But aside from Chair (and Rufus-Lily), romantic change is in the air when Gossip Girl kicks off its third season Monday night. The promotional pictures we've seen and spoilers we've read hint at a bevy of hot new couples.

From familiar face Carter Baizen to newcomers Olivia, Scott and Bree, our favorite characters will be getting involved with new love interests left and right.

Which new pair are you most excited for? Vote in our survey below ...

Which couple are you most excited to see in Season 3?

Steve Marsi is the Managing Editor of TV Fanatic. Follow him on Google+ or email him here.