When Life Unexpected returns for its second season, the union of Ryan and Cate won't be this show's only change.

It also moves to Tuesday nights, as The CW pairs the series with One Tree Hill in the hopes of creating a new, popular block of programming.

As for Life Unexpected spoilers, producers have hinted that Cate and Baze will still have a chance together... although the latter will also meet a pair of new love interests. They'll be played by Arielle Kebbel and Amy Price-Francis, both of whom are featured in the season premiere photos below.

Titled "Ocean Uncharted," the Life Unexpected season two premiere airs on September 14.

Along with these pictures, you can feast your eyes on images from the One Tree Hill season eight premiere HERE.

Matt Richenthal is the Editor in Chief of TV Fanatic. Follow him on Twitter and on Google+.