Beat the Devil Scene
Lightman believes the student of his mentor is a psychopath in the episode "Beat the Devil." He tries to convince her of that here.

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Lie to Me
Lie to Me Season 2 Episode 11: "Beat the Devil"
Dr. Cal Lightman
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Lie to Me Photos, Lie to Me Season 2 Episode 11 Photos, Dr. Cal Lightman Photos
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Lie to Me Season 2 Episode 11 Quotes

Ria Torres: You really want to take this case?
Eli Loker: What, is the guy and eccentric? Yes, big time. But so am I, have you seen this shirt.

Here's the problem, Martin Walker is a psychopath and probably a killer. Just though you should know.

Cal Lightman