Because Samantha has no memories of the past, including her sexual experiences, she's faced with the decision of waiting this time for the right guy to come along, or to experiment. Such are the tough choices someone with amnesia faces.

Samantha Who?
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Samantha Who? Season 1 Episode 4 Quotes

Samantha: So she's hum, she seems nice... She's very pretty.
Todd: Oh, thanks.
Samantha: I didn't say you were pretty! I said she was pretty.

Samantha: Mom, can I talk to you about something kind of personal?
Regina: Oh, I knew this was going to come up sooner or later.
Samantha: You did?
Regina: Yes, and hunny, don't worry... you're not dying, this happens to every woman, once a month.