Daenerys & Daario (Game of Thrones)
Ever since they got the newer (hotter) Daario, we've been way more into this pairing than ever before. Dany commanding Daario to take his clothes off and then watching him undress like a Queen on her throne was hot as hell. They haven't fallen back in bed together again yet - at least not on screen - but we have a sneaking suspicion they will.
Wick & Raven (The 100)
"Let's get our stoichiometry on" is simultaneously the weirdest and most wonderful pick up line of all time. Wick and Raven certainly have chemistry, and it exploded all over our screens on this season of The 100. Raven seemed to want to brush it off like it was nothing, but we think Wick will be harder to shake than that.
Klaus & Caroline (The Vampire Diaries/The Originals)
Klaroline got one extra steamy hookup in the woods before they were tragically separated onto different shows for the rest of eternity. Not a very satisfying conclusion for two years of buildup if you ask us. Don't worry, there's always hope that Caroline will one day make her way down to New Orleans to give this couple the ending they deserve.
Scarlett & Gunnar (Nashville)
For the love of country music, can these two just get back together already? After a short relationship and a denied proposal, Scarlett and Gunnar went their separate ways, both romantically and musically. Recent events have pulled them closer together though, so they might be headed back towards relationship-ville soon.
Hayley & Elijah (The Originals)
This couple just can't catch a break. Whether it's a secret love child or a mystical werewolf wedding, something always gets between them. After a poorly timed confession and a ridiculously hot sex scene, Hayley and Elijah pretty much called it quits. Nevertheless, we expect they'll stumble into another forbidden love scene soon.
Regina & Robin Hood (Once Upon a Time)
That pesky town line is driving everyone apart on Once Upon a Time. Robin had to cross into the real world and leave his true love, Regina, behind in order to keep his family together. We can't see how he'll ever make it back with Marian's life depending on them staying away, but we still believe that true love conquers all.
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