Mal and Zoe - Firefly
Zoe was Mal's first mate and closest friend. They had been through war together and knew each other like the backs of their own hands. Zoe was also happily married to Serenity's goofy, fun-loving pilot Wash, while Mal was busy denying his love for resident courtesan Inara. Mal once endured extended torture so Zoe could save her less-torture-resilient husband before charging back to save him. These two always knew they could rely on one another, no matter what.

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Firefly Quotes

Mal: You're only going to scare him.
Jayne: Pain is scary.

Mal: I gotta know how close the Alliance is, exactly how much you told them before Wash scrambled your call. So I've given Jayne here the job of finding out.
Jayne: He was non-specific as to how.