Mal and Zoe - Firefly
Zoe was Mal's first mate and closest friend. They had been through war together and knew each other like the backs of their own hands. Zoe was also happily married to Serenity's goofy, fun-loving pilot Wash, while Mal was busy denying his love for resident courtesan Inara. Mal once endured extended torture so Zoe could save her less-torture-resilient husband before charging back to save him. These two always knew they could rely on one another, no matter what.

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FOX
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Firefly
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Firefly Quotes

If your hand touches metal, I swear by my pretty floral bonnet I will end you.

Mal

Simon: How do I know you won't kill me in my sleep?
Mal: You don't know me son, so let me explain this to you once. If I ever kill you, you'll be awake, you'll be facing me, and you'll be armed.