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Chuck gets a flash the lets him know an arms dealer known as "La Ciudad" will be at an art auction.  Chuck infiltrates the party with Sarah and tries to identify the dealer.  While there, Chuck ends up dancing the Tango with a Latin woman, Malena, who ends up being La Ciudad.

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Chuck Season 1 Episode 3 Quotes

Chuck: Okay, this is my first foray into major undercover spy work. So, you could ease up on the sarcasm, that would be great. And, how am I supposed to recognize La Ciudad? Is there a picture or something?
Casey: If there was a photograph, why would we need you?
Chuck: What did we just talk about?
Casey: Oh, I'm sorry. We're hoping something at the event triggers a flash.
Chuck: See, that's all you had to say

Chuck: I'm sorry guys. And Anna.
Anna: "Guys" is fine, I don't mind.
Chuck: No, it's not right, we need to come up with something non-gender-specific. How do we feel about "team?"
Anna: The little Nerd-Herders?
Lester: Chuck's Stable of Hoes?