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I really don't like this union at all though!!
I don't care whether they have as you call it, "empty sex". If it happens, there's bound to be repercussions on either one or both sides of the party. Imagine if Blair found out, she wouldn't have the same respect for Chuck, or if Nate knew about Vanessa, he probably wouldn't be able to handle it either.
Also, I could see Vanessa falling for Chuck/might feel that there's a connection between them as a result of being lured by Chuck's charming ways.
I'm not a fan of any C/V interaction, but if it's an attempt to make Nair jealous, with no side effects of Chuck falling for Vanessa, then I'm all for it - but there has to be NO side effects. I hope the experience turns him off in every way from her.