Smallville Green Arrow
Green Arrow makes his first Smallville appearance in episode four of season six.

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https://www.youtube.com/watch?v=39qz600f7R0
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Smallville Quotes

Clark: Isn't it time we moved beyond these mental trials?
Jor-El: Your determination is strong, Son, but just as your passion will be your greatest strength, so, too, will it be your greatest obstacle.

Chloe: Dr. Hamilton.
Dr. Hamilton: If you would be so kind as to lower the 9mm Jericho 941. I prefer "Emil."