You're looking at a scene from "It's Really Complicated." It's the 12/3/12 episode of Gossip Girl.
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It's all on the line for Waldorf Designs this fall. Here we see Blair's big event in a photo from Gossip Girl Season 6 Episode 7, "Save the Last Chance."
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Chuck and Blair in a photo from Gossip Girl Season 6 Episode 7, "Save the Last Chance."
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Dan and Serena in a photo from Gossip Girl Season 6 Episode 7, "Save the Last Chance."
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Blair and Nelly Yuki in a photo from Gossip Girl Season 6 Episode 7.
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Blair and Dorota in a photo from Gossip Girl Season 6 Episode 7.
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Blair and Serena appear to be on better terms in a photo from Gossip Girl Season 6 Episode 7.
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Serena and Blair in a photo from Gossip Girl Season 6 Episode 7.
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Gossip Girl Quotes

Blair: Fashion is the most powerful art there is. It's movement, design and architecture all in one. It shows the world who we are and who we'd like to be. Just like your scarf suggests that you'd like to sell used cars.
Dan: Vanessa gave me this scarf.

[to Jenny] That's the thing. You need to be cool to be queen. Anne Boleyn thought only with her heart and she got her head chopped off. So her daughter Elizabeth made a vow never to marry a man. She married a country. Forget boys. Keep your eye on the prize, Jenny Humphrey. You can't make people love you, but you can make them fear you. For what it's worth, you're my Queen. I choose you.

Blair