Valentina enters the picture on the episode "Green Star." This character is the head of the San Francisco Mai.
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The Nine Lives of Chloe King Season 1 Episode 3 Quotes

Paul: You'll be fine, you just have to relax.
Chloe: Why is that the universal boy solution to pretty much everything?

Alek: You do seem a little...tense.
Chloe: Deranged psycho killer is still after me so, yeah, maybe a little.