It turns out Chuck's neighbor in the suburbs, Syliva (Jenny McCarthy) wasn't interested in sleeping with him at all. She just wanted to hook him up to this machine and test out the Dark Intersect on him!

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Chuck
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Chuck Season 2 Episode 13: "Chuck Versus the Suburbs"
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Chuck Season 2 Episode 13 Quotes

Lester: Hey! How was the big date?
Big Mike: Gentlemen. It was a night of exquisite passion. I did things with that woman I didn't even know existed, which are likely illegal.
Lester: Yes! So you took our advice?
Big Mike: I lied my ass off.

Chuck: Are you enjoying this whole Martha Stewart thing? (laughs) I can't believe it. Please tell me you're not going soft on me.
Sarah: Just shut up and eat your breakfast.
Chuck: You better be careful, Sarah. One day, you might actually turn into a real girl.