Social Suicide  - Buffy the Vampire Slayer Season 1 Episode 1
It is hard to recover from trying to kill the most popular girl in school with a stake, even if it was an accident.

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The WB
Show:
Buffy the Vampire Slayer
Episode:
Buffy the Vampire Slayer Season 1 Episode 1: "Welcome to the Hellmouth"
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Buffy the Vampire Slayer Season 1 Episode 1 Quotes

Cordelia: You'll be okay here. If you hang with me and mine, you'll be accepted in no time. Of course, we do have to test your coolness factor. You're from L.A., so you can skip the written. So let's see...vamp nail polish?
Buffy: Over?
Cordelia: So over. James Spader?
Buffy: He needs to call me!
Cordelia: Frappachinos?
Buffy: Trendy but tasty.
Cordelia: Josh Tesh.
Buffy: The devil.
Cordelia: That was pretty much a gimme, but you passed!

Joyce: Okay, have a good time! I know you're going to make friends right away, just think positive.
[Buffy leaves the car]
Joyce: And honey...
[Buffy turns around]
Joyce: Try not to get kicked out.
Buffy: I promise.