Brook and Poussey - Orange is the New Black
Brook and Poussey developed a friendship in the third season of Orange is the New Black after Brook becomes depressed and tries to overdose. Beginning in the fourth season, the two are seen to be happy and dating, but their relationship ends rather tragically when Poussey is killed by a guard.
Wes and Laurel - How to Get Away With Murder
The two had the strongest friendship out of The Keating Five, being deemed ‘the quiet ones’, but in the second season, they share a steamy kiss and eventually begin a relationship in the third season before Wes’ death.
Lucas and Max - Stranger Things
While Lucas and Max may be young, they develop a close friendship in Stranger Things’ second season and share a kiss in the season finale, hinting at a possible relationship.
Scott and Kira - Teen Wolf
While there species, fox and werewolf, are known rivals, these two had no problems connecting. After Kira is introduced as the new girl in school, she is included in the pack and eventually becomes Scott’s girlfriend before her departure from the show.
James and Lena - Supergirl
James started off disliking Lena for her associating to her brother Lex, but as the two starting spending more time together, James realized that she wasn’t like her brother at all and they developed a romantic relationship until the middle of the fourth season.