First, Hot Look: Olivia Munn on Chuck Season Premiere

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The guest star heavy fourth season of Chuck gets underway on September 20... in gorgeous fashion.

Olivia Munn comes aboard the NBC series in the role of CIA operative Greta, a role that will actually change throughout the season and later be played by Stacy Keibler and Isaiah Mustafa.

In the premiere pics below, it's clear the Burbank Buy More has recovered from last season's events, thanks to help from the CIA, which will be running the store this fall. Check out a couple photos from "Chuck vs. the Anniversary" and visit our Chuck spoilers section for a more thorough look at season four:

Olivia Munn on Chuck
Munn as Greta

Matt Richenthal is the Editor in Chief of TV Fanatic. Follow him on Twitter and on Google+.

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Chuck Quotes

Sarah: Wow, I didn't think people still named their kids Chuck. Or Morgan, for that matter.
Chuck: My parents were sadists, and carnival freaks found him in a dumpster.
Morgan: But they raised me as one of their own!

Chuck: Uh, you know, Sis, the thing is, Morgan and I don't really feel like we're fitting in...at my birthday party...'cause we don't know anybody, 'cause they're all your friends, and they all happen to be doctors.
Morgan: Doctors who don't really get our jokes!
Chuck: Well, your jokes

Chuck Music

  Song Artist
Wait It Out Imogen Heap iTunes
Black and Gold Sam Sparro iTunes
Just Dropped In (To See What Condition My Condition Is In) Kenny Rogers iTunes