In this scene from "Summer, Kind of Wonderful," Catherine is the new woman - the older woman - that has stolen Nate Archibald's heart. Or at least his ... you know.

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The CW
Show:
Gossip Girl
Episode:
Gossip Girl Season 2 Episode 1: "Summer, Kind of Wonderful"
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Gossip Girl Season 2 Episode 1 Quotes

Serena: Blair will never forgive you for what you did to her.
Chuck: Who told you that little piece of advice, your boyfriend Nate?
Serena: Nate didn't say anything ...
Chuck: Good. I don't think it's wise taking relationship advice from someone in a FAKE relationship. Call me crazy. (pause) Enjoy another night alone with your thoughts.
Serena: Good luck on your suicide mission!

Serena: I still miss Dan sometimes... more than sometimes.
Blair: The only thing lamer than dating Dan Humphrey... is mourning Dan Humphrey.