This is a photo from Season 1 of The Blacklist. It is from the episode "Frederick Barnes."
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Liz and the FBI work to find the criminal behind a subway attack on The Blacklist. "Frederick Barnes" is the seventh episode of the show's first season.
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The Blacklist Season 1 Episode 7 Quotes

Red's Driver: Did he take the bait?
Red: Like a trout to a butterworm.

Perhaps this day can be salvaged after all.

Red