This is a photo from "And the ATM." It's Episode 18 from Season 3 of 2 Broke Girls.
Now that Deke's secret is revealed, Max decides to break up with him on 2 Broke Girls. "And the ATM" is the 16th episode of the show's third season.

2 Broke Girls Season 3 Episode 16 Quotes

Han: Be careful, you’re the very first.
Max: We know how long you've been waiting to say that to a woman.

Deke, you can’t be my boyfriend. From now on, I’m like Welfare. You have to be broke to get some.