Sam and Dean are on the case in this Supernatural still. It's from the episode "There Will Be Blood."
It's Crowley! What Supernatural fan out there does not get excited when this character makes an appearance?

Supernatural Season 7 Episode 22 Quotes

Dean: Don't say pie.
Sam: Definitely pie.
Dean: Bastards.

Dean: Ok, I've read this more times than the Playboy I found in dad's duffel.
Sam: Anna Nicole?
Dean: Anna Nicole.